Oddelenie environmentálnej fyziky - Prihlásený: igor
Katedra astronómie, fyziky Zeme a meteorológie, FMFI UK, Bratislava,

Conversion of CH4 to CO and oxygenates from model exhaust gases by discharges of streamer-to-spark transition type

Janda M., Kunecová D., Machala Z., Morvová M.
19th International Symposium on Plasma Chemistry ISPC 19, Bochum (Germany), July 26-31, CD-ROM (2009)

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Abstrakt:

We investigated a conversion of CH4 into oxygenates or CO by a transient spark discharge operating above water in N2/CO2/CH4 mixtures at atmospheric pressure. The emission of N2(C), N2(B), N2+, CN, CH, C2, OH, NH, N, O, H, and C species was detected by emission spectroscopy. Gaseous products detected by infrared spectroscopy were CO and acetylene. Methanol and acetaldehyde were identified in the liquid phase.