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Abstrakt: The municipal waste carbonisation inside high temperature combustion chamber using direct heating by exhaust gas flow in oxygen free atmosphere is an interesting alternative in waste management scenario. The process has a lot of similarities with biomass pyrolysis. At lover temperatures (~350 C) the main process is cracking, producing liquid hydrocarbons as levoglucosane and similar tar compounds, then at temperatures (~650 C) hydrogen is formed, at high temperatures (~950 C) the carbon char/active carbon is formed instead of ash. The heat from the process can be recuperated.The method for flue gas cleaning with possible application to combustion and carbonization process uses non-thermal plasma based pilot system for 50-250 m3/hour of gas flow. The applied method cleaned very efficiently the exhaust gas from variety of non-wanted compounds, utilises whole combustion exhaust. CO2 removal efficiency is as high as 40-99%. The process is connected with nitrogen fixation, removal of NOx, VOC, PAH, -SH and SOx, PCDD, PCDF and other is done with high efficiency and without wastewater production. The final solid amino acids condensation product (proteinoid) made in electric discharge seems to be convenient as nitrogen containing fertiliser.
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Citácie: | 1.) | Ferrari, V., Nazari, M.T., Da Silva, N.F., Crestani, L., Raymundo, L.M., Dotto, G.L., Piccin, J.S., Oliveira, L.F.S., Bernardes, A.M., 2024. Pyrolysis: a promising technology for agricultural waste conversion into value-added products. Environ Dev Sustain. https://doi.org/10.1007/s10668-024-04760-w
(2023)
------------- | | 2.) | Eva Chmielewská, An Update of Zeolitic and Other Traditional Adsorption and Ion Exchange Materials in Water Cleanup Processes, In: Handbook of Natural Zeolites, Editor(s): Vassilis J. Inglezakis and Antonis A. Zorpas, eISBN: 978-1-60805-261-5 ISBN: 978-1-60805-446-6, pp. 436-452 (17), Bentham Science Publishers (2012)
(2012)
------------- | | 3.) | Tan, Z., Lagerkvist, A.,Phosphorus recovery from the biomass ash: A review, Renewable and Sustainable Energy Reviews 15 (8) , pp. 3588-3602 (2011)
(2011)
------------- | | 4.) | Siváček I., Aplikácia röntgenofluorescenčnej analýzy v životnom prostredí, Študentská vedecká konferencia, Bratislava, Apríl 2009
(2010)
------------- | | 5.) | Chmielewska, E., Sabova, L., Jesenak, K., Study of adsorption phenomena ongoing onto clinoptilolite with the immobilized interfaces, Journal of Thermal Analysis and Calorimetry 92 (2), pp. 567-571 (2008) SCI/SCOPUS
(2008)
------------- | | 6.) | Chmielewská, E. - Sabová, L. - Gáplovská, K. - Čaplovičová, M. : In: Functionally graded mesoporous zeolitic adsorbents in order to promote the pollutants removal. Kuwait Journal of Science & Engineering, Vol. 35, No. 2B, 2008. s. 127-142 - SCOPUS
(2008)
------------- | | 7.) | Chmielewska, E. : In: XPS, NMR and SBET studies of native clinoptilolite functionalized with carbonaceous substances. Research Journal of Chemistry and Environment, Vol. 11, No. 3, 2007. s. 65-71 - SCI/SCOPUS
(2007)
------------- | | 8.) | Locke, B. R. - Sato, M. - Sunka, P. - Hoffmann, M. R. - Chang, J. S. : In: Electrohydraulic discharge and nonthermal plasma for water treatment. Industrial & Engineering Chemistry Research, Vol. 45, No. 3, 2006. s. 882-905 - SCI; SCOPUS
(2006)
------------- | | 9.) | Chmielewska, E. - Pilchowski, K. : In: Surface modifications of natural clinoptilolite-dominated zeolite for phenolic pollutant mitigation. Chemical Papers, Vol. 60, No. 2, 2006. s. 98-101 - SCI; SCOPUS
(2006)
------------- | | 10.) | Gmucova, K. - Chitu, L. - Majkova, E. - Satka, A. - Giersig, M. - Hilgendorff, M. : In: Electrochemistry of a carbon microfiber adsorbed by cobalt nanoparticles. Analytical Sciences, Vol. 21, No. 10, 2005. s. 1227-1232 - SCI ; SCOPUS
(2005)
------------- | | 11.) | Chmielewska, E. - Sabova, L. : In: Contemporary and prospects for new generation of environmental nanocomposed zeoadsorbents. Petroleum & Coal, Vol. 47, No. 3, 2005. s. 6-9
(2005)
------------- | | 12.) | Turčániová, L. - Kadarová, J. - Imrich, P. - Liptaj, T. - Vidlar, J. - Vašek, J. - Foldyna, F. - Sitek, J. - Baláž, P. : In: Reactivity of mechanical activated coals for special utilization. Journal of Materials Science, Vol. 39, No. 16-17, 2004. s. 5467-5470 - SCI-nepriamo
(2004)
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