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Division of Environmental Physics - Students
Faculty of Mathematics, Physics and Informatics, Comenius University Bratislava

Students



Mária CÍBIKOVÁ
MSc. student



MSc. study
2019 - 2021

Supervisor: Karol Hensel
Consultant: Richard Cimerman
Title:
Selected aspects of naphthalene removal in plasma and catalyst systems
Abstract:


Bc. study
2018 - 2019

Supervisor: Karol Hensel
Consultant: Richard Cimerman
Title:
The effect of BaTiO3 a ZrO2 on naphtalene removal by plasma catalysis
Abstract:
Biomass is one of the alternative sources which can be used to produce energy without using fossil fuels that are harmful to a human health and have unfavorable environmental impact. Energy can be obtained by gasification or combustion processes of the biomass. The gasification leads to production of syngas, that also contains pollutants including tars. The tars inhibit the syngas utilization and it is necessary to remove them. In the process of combustion of biomass, pollutants are also produced including tars, although in much smaller amounts, but still they must be removed. Tars are a mixture of hydrocarbons with one or more benzene rings. They are highly toxic, carcinogenic, and may cause many technical problems in devices. The tars produced by gasification must be removed by using reduction process in order not to degrade the syngas. Tars formed in the combustion process can be removed also by oxidation processes as exhaust gas has no value and only gas cleaning before its release to the atmosphere is necessary. In this study we dealed with the removal of tar by using plasma combined with ZrO2 and BaTiO3 catalysts in the form of pellets. Naphthalene was used as a model polyaromatic tar compound. Firstly we studied the electric and optical characteristics of plasma-catalytic reactors. Next we observed chemical changes in the gas caused by dicharge combined with catalyst for different frequencies and amplitudes of the applied voltage. We analyzed naphthalene removal efficiency and formation of the gaseous and solid by-products by using infrared and X-ray spectroscopy. The results show that the plasma-catalysis is more efficient in naphthalene removal as well as have better selectivity in comparison to plasma. BaTiO3 was more efficient than ZrO2 with higher frequency and lower energy were used. When tested repeatedly, BaTiO3 shown better durability and catalytic activity as well. On the other hand ZrO2 was very efficient in combination with lower frequency and had better absorption properties. Aside from that we also noticed higher production rate of desired products. In general we can conclude that plasma combined with catalyst has high efficiency and it can be considered to be effective method of tars removal.


Active

  Mária CÍBIKOVÁ

  Mostafa E. HASSAN

  Axel HENNECKE

  Daniel JAKUBČIN

  Radoslav JANKOVIČ

  Jana KŠANOVÁ

  Katarína KUČEROVÁ, born Tarabová

  Aleksandra Y. LAVRIKOVA

  Jakub MASLÍK

  Emanuel MAŤÁŠ

  Robin MENTHÉOUR

  Gervais B. NDIFFO YEMELI

  Veronika OKRUHLICOVÁ

  Slavomir PÁSZTOR

  Dominika SERSENOVÁ

  Patrik ŠTÍPALA

  Peter TÓTH

Alumni

  

  Daniela BARTKOVÁ

  Hana BUCHHOLCEROVÁ

  Richard CIMERMAN

  Veronika DRENINOVÁ, born Biskupičová

  Lukáš DVONČ

  Július GÁLIK

  Dušan GIERTL

  Paulína HALUŠKOVÁ

  Lenka CHLÁDEKOVÁ

  Patrícia IVANOVÁ

  Karolína JANÍKOVÁ

  Igor JEDLOVSKÝ

  Matej KINTLER

  Matej KOVÁČ

  Zuzana KOVAĽOVÁ, born Šipoldová

  Daniela KUNECOVÁ

  Lenka LEŠTINSKÁ

  Michal LEŠTINSKÝ

  Dominika MIHÁLIKOVÁ

  Pavol MIŠENKO

  Matej MOLNÁR

  Adriana NIKLOVÁ

  Samuel OMASTA

  Lucia PAKOSOVÁ

  Marek PAVLE

  Michal PELACH

  Adam POLAKOVIČ

  Branislav PONGRÁC

  Milan PRAČKO

  Diana RAČKOVÁ

  Martin SELVEK

  Jozef SIČ

  Lucia STRIŽENCOVÁ

  Anna SUČANSKÁ

  Barbora TARABOVÁ

  Pavol VALOVIČ

  Martina VELÍSKOVÁ

  Veronika ZÁŇOVÁ

  Juraj ZIGO

  Andrea ŽILKOVÁ


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